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The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions

Received: 21 October 2019     Accepted: 14 November 2019     Published: 13 April 2020
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Abstract

The aim of study was to reduce chemical contaminant from water and wastewater by adopting low-cost adsorption process over modified fly ash, which prepared easily by two methods, alkaline added under hydrothermal conditions, some physio-chemical technique used to characterize the modified fly ash as XRF, XRD, BET technique and scanning electron microscopy SEM. The result showed that the modified fly ash has crystal structure hexagonal and it attributed to zeolite A, the regarding of crystal structure, specific surface area and external morphology examined by SEM, the estimation of specific surface area affiliated to type (IIB) isotherm which is similar to non-porous or macroporous materials, finding results showed that the modified fly ash described better to both Freundlich and Langmuir model isotherm for removal mechanism, the maximum adsorption capacity qmax for Zn2+ an Fe2+ is 114.2 and 196.7 mg/L respectively, furthermore, iron and zinc ions removed well by direct method SZ1 due to the crystal lattice structure, big surface area and pore size 49.317 and 38.813 m2/g respectively, finally modified fly ash can be used as low-cost adsorption material due to the nature of ion- exchange and performance in adsorption according to their big surface area.

Published in Modern Chemistry (Volume 8, Issue 1)
DOI 10.11648/j.mc.20200801.13
Page(s) 12-17
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Fly Ash, Modified Fly Ash, Adsorption, Isotherm, Marco-porous

References
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    Mohammed Sulieman Ali Eltoum, Sahl Yasin. (2020). The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions. Modern Chemistry, 8(1), 12-17. https://doi.org/10.11648/j.mc.20200801.13

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    ACS Style

    Mohammed Sulieman Ali Eltoum; Sahl Yasin. The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions. Mod. Chem. 2020, 8(1), 12-17. doi: 10.11648/j.mc.20200801.13

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    AMA Style

    Mohammed Sulieman Ali Eltoum, Sahl Yasin. The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions. Mod Chem. 2020;8(1):12-17. doi: 10.11648/j.mc.20200801.13

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  • @article{10.11648/j.mc.20200801.13,
      author = {Mohammed Sulieman Ali Eltoum and Sahl Yasin},
      title = {The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions},
      journal = {Modern Chemistry},
      volume = {8},
      number = {1},
      pages = {12-17},
      doi = {10.11648/j.mc.20200801.13},
      url = {https://doi.org/10.11648/j.mc.20200801.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20200801.13},
      abstract = {The aim of study was to reduce chemical contaminant from water and wastewater by adopting low-cost adsorption process over modified fly ash, which prepared easily by two methods, alkaline added under hydrothermal conditions, some physio-chemical technique used to characterize the modified fly ash as XRF, XRD, BET technique and scanning electron microscopy SEM. The result showed that the modified fly ash has crystal structure hexagonal and it attributed to zeolite A, the regarding of crystal structure, specific surface area and external morphology examined by SEM, the estimation of specific surface area affiliated to type (IIB) isotherm which is similar to non-porous or macroporous materials, finding results showed that the modified fly ash described better to both Freundlich and Langmuir model isotherm for removal mechanism, the maximum adsorption capacity qmax for Zn2+ an Fe2+ is 114.2 and 196.7 mg/L respectively, furthermore, iron and zinc ions removed well by direct method SZ1 due to the crystal lattice structure, big surface area and pore size 49.317 and 38.813 m2/g respectively, finally modified fly ash can be used as low-cost adsorption material due to the nature of ion- exchange and performance in adsorption according to their big surface area.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - The Adsorption Efficiency of Modified Fly Ash for the Removal of Iron and Zinc Ions
    AU  - Mohammed Sulieman Ali Eltoum
    AU  - Sahl Yasin
    Y1  - 2020/04/13
    PY  - 2020
    N1  - https://doi.org/10.11648/j.mc.20200801.13
    DO  - 10.11648/j.mc.20200801.13
    T2  - Modern Chemistry
    JF  - Modern Chemistry
    JO  - Modern Chemistry
    SP  - 12
    EP  - 17
    PB  - Science Publishing Group
    SN  - 2329-180X
    UR  - https://doi.org/10.11648/j.mc.20200801.13
    AB  - The aim of study was to reduce chemical contaminant from water and wastewater by adopting low-cost adsorption process over modified fly ash, which prepared easily by two methods, alkaline added under hydrothermal conditions, some physio-chemical technique used to characterize the modified fly ash as XRF, XRD, BET technique and scanning electron microscopy SEM. The result showed that the modified fly ash has crystal structure hexagonal and it attributed to zeolite A, the regarding of crystal structure, specific surface area and external morphology examined by SEM, the estimation of specific surface area affiliated to type (IIB) isotherm which is similar to non-porous or macroporous materials, finding results showed that the modified fly ash described better to both Freundlich and Langmuir model isotherm for removal mechanism, the maximum adsorption capacity qmax for Zn2+ an Fe2+ is 114.2 and 196.7 mg/L respectively, furthermore, iron and zinc ions removed well by direct method SZ1 due to the crystal lattice structure, big surface area and pore size 49.317 and 38.813 m2/g respectively, finally modified fly ash can be used as low-cost adsorption material due to the nature of ion- exchange and performance in adsorption according to their big surface area.
    VL  - 8
    IS  - 1
    ER  - 

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Author Information
  • Chemistry Department, Sudan University of Science and Technology, Khartoum, Sudan

  • Sudanese Chemical Society, Khartoum, Sudan

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